Show simple item record

dc.contributor.advisorDeardorff, Don
dc.contributor.authorCollier, Summer
dc.contributor.authorCarter, Caroline
dc.date.accessioned2020-08-13T14:55:50Z
dc.date.available2020-08-13T14:55:50Z
dc.date.issued1999-01-01 0:00
dc.identifier.urihttps://scholar.oxy.edu/handle/20.500.12711/541
dc.description.abstractThe overarching goal of this research is the development of synthetic methodologies that permit facile, enantiocontrolled access to molecules of biological importance, more specifically, imidate (1) derived from enantiomerically pure a,b-unsaturated cynanohydrins. Currently substrates with five different R-groups are under study. Predisposition of 1 to palladium(II) catalyzes the stereospecific rearrangement in a [3,3]-sigmatropic shift to form the related acetamide (2). So far, this reaction has been shown to form only trans double bonds. These novel products, with their multitude of functional groups, offer great versatility as building blocks for pharmaceutical drugs.
dc.titleStudies directed towards the Synthesis of Enantio-enriched a,b-Unsaturated Imidates and their Application in a Cyclic Intermediate [3,3]-Sigmatropic Shift Summer Collier and Caroline Carter
dc.typearticle
dc.abstract.formathtml
dc.description.departmentchem
dc.source.issueurc_student
dc.source.issueurc_student
dc.identifier.legacyhttps://scholar.oxy.edu/urc_student/167
dc.source.statuspublished


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record